Household Solvents and Paint Strippers: Common Hazardous Wastes in Every Home
Handling Wastes:
Household Solvents
From paint stripper to nail pollish remover, household solvents are all too common throughout every home. A solvent is a substance that
dissolves another substance forming a solution. Solvents that contain carbon are
known as organic solvents and can contain chemicals considered hazardous -- they
can be flammable and toxic. Some household maintenance and cleaning products
contain organic solvents such as petroleum distillates. These are sometimes used
to dissolve difficult stains or greases on certain materials that may be damaged
by water-based cleaners.
Organic solvents are used in
household maintenance items as a carrier, thinner, and remover. However, wastes
and leftovers can result in potentially hazardous household waste. For example,
one cup of trichloroethylene, a solvent sometimes found in household cleaners or
maintenance items, can contaminate about three million gallons of water.
Hazards of Solvents
Organic solvents can
produce the following environmental and health hazards when used, stored, or
incorrectly disposed.
Environmental
Health
Identifying Products
Containing Organic Solvents
Even though the labels may
not clearly state that the product contains an organic solvent, they do give
indicators such as the terms FLAMMABLE, COMBUSTIBLE or CONTAINS PETROLEUM
DISTILLATES. Solvents may have a distinct odor. If your product meets one or
more of the following criteria, it may contain an organic solvent.
-
it hardens or
evaporates rapidly on the surface after application (polishes, waxes)
-
strong
"solvent" odor such as gas or kerosene odor
-
contains petroleum
distillates
-
the label says the
product is flammable
-
the label says
breathing vapors may be harmful
Understanding the general
types of products that may contain solvents can remind us to read the
manufacturer's label for additional information in selection and safe use,
storage and disposal. A list of products that may contain organic solvents is
provided for identifying such products:
Generally 100 percent
organic solvents:
-
Furniture stripper
-
Turpentine
-
Charcoal lighter fluid
-
Drycleaning fluids
-
Paint thinner
-
Nail polish remover
-
Degreasers
-
Lubricating Oils
-
Fuels
May be partially
solvent-based (some are water or detergent based)
-
Furniture oils,
polishes, wax
-
Shoe care products
-
Spot removers
-
Rug and upholstery spot
remover cleaners
-
Glues/adhesives
-
Metal and wood cleaners
-
Paints
-
Wood finishes (varnish,
shellac, stain)
Some examples of label key
words indicating the presence of organic solvents:
-
Benzene
-
carbon tetrachloride*
-
chlorinated solvents
-
diethyl or dimethyl
phthalate
-
methylene chloride
-
paradichlorobenzene
-
perchloroethylene (or
tetrachloroethylene)
-
petroleum distillates
-
phenol. toluene
(mineral spirits)
-
1,1,1 trichloroethane
-
xylene
(*No longer permitted in
products for home use.)
Prevention of Household
Hazardous Waste
To reduce household
hazardous waste, start with prevention.
-
Buy only what you need.
-
Buy the most
appropriate product for the job and the least hazardous product -- use
alternative less hazardous products.
-
Check to see if you
already have the product on hand before buying more.
-
Ask if a neighbor has
some of the leftover product you can use up.
Use Less Hazardous
Products
-
Where appropriate, use
water-based rather than organic solvent-based adhesives, cleaners, paints,
finishes, etc.
-
Caution or warning
usually imply less hazard than danger or poison on the product label.
-
Use mechanical devices
if possible such as drain plunger or plumber's snake when appropriate for
the job.
Managing and Disposing
of Solvents
Completely use up the
solvent or share it with others to use if safe to do so. Household
hazardous waste collections in a limited number of communities are held to
specifically manage household hazardous products. If it is not possible to
take the product to a household hazardous waste collection site or to
completely use up the solvent and only small quantities remain (quantities
so small as to be unusable), it may be evaporated. Evaporate the solvent
in small quantities allowing the residue, if any, to harden for disposal
either at a hazardous waste collection or permitted sanitary landfill if
accepted. Do not burn the hardened residue as the residue may give off
toxic fumes, leave a toxic residue or be dangerous to burn.
If the solvent is in an
aerosol form, use up or give away for others to use up. Place the empty
container in the trash for disposal in a permitted sanitary landfill. Be
very careful of potential combustion and do not breath the vapors.
To evaporate:
(Evaporation may not be recommended in some areas due to air quality
issues.)
-
Move the container
to a secure, sheltered outdoor area away from spark sources or flames,
children and pets.
-
Open the lid and
allow liquid to dry.
-
Discard hardened
residue at household hazardous waste collection or in trash if
permissible by transfer station or landfill.
Solvents flushed in a
community waste water treatment system or a home septic system may
interfere with the normal biodegradation process. Toxic solvents can pass
through the system unchanged to be discharged directly into the drainfield
soil and might move back into well water. Septic systems can only
partially treat chemical wastes.
Technically, most
household waste is exempt under RCRA hazardous waste regulations. However,
householders should manage potentially hazardous household waste
responsibly.
References
Andrews, E. (1989) Paint and
Other Home Improvement Products. (G3554) Madison, WI: University of
Wisconsin-Extension.
Lund, H. (1993). The
McGraw-Hill recycling handbook. NY: McGraw-Hill.
Proceedings of the National
EPA Conference on Household Hazardous Waste (1990,1991,1992,1993,1994). Andover
MA: Dana Duxbury & Associates.
Disposal Do it Right.
Household Products Disposal Council.
Nebraska University Cooperative Extension
by Shirley Niemeyer,
Extension Specialist, Home Environment
Kathleen Heiden, Graduate Student, UN-L
Wayne Woldt, Extension Specialist, Waste Management
What You Should Know About Using Paint Strippers
IF NOT PROPERLY USED, PAINT STRIPPERS ARE HAZARDOUS TO YOUR
HEALTH AND SAFETY.
Paint strippers contain chemicals that loosen paint from
surfaces. These chemicals can harm you if not used properly.
Some paint stripping chemicals can irritate the skin and eyes, or
cause headaches, drowsiness, nausea, dizziness, or loss of
coordination. Some may cause cancer, reproductive problems, or
damage of the liver, kidney, or brain. Others catch fire easily.
Proper handling and use of paint strippers will reduce your
exposure to these chemicals and lessen your health risk.
GENERAL SAFETY PRECAUTIONS
Paint strippers contain different chemicals, and the
potential hazards are different for various products. Each
product has specific safety precautions (see the section below on
paint stripper types). However, there are some general safety
steps to keep in mind when using any paint stripper. If you use
paint strippers frequently, it is particularly important that you
follow these steps:
1. Always read and follow all the instructions and safety
precautions on the label. Do not assume you already
know how to use the product. The hazards may be
different from one product to another, and the
ingredients in individual products often change over
time. The label tells you what actions you should take
to reduce hazards and the first aid measures to use.
2. Wear chemical-resistant gloves appropriate to the type
of stripper being used (see manufacturer's
instructions). Common kitchen latex gloves do not
provide enough protection.
3. Avoid getting the paint stripper on your skin or in
your eyes. Wear protective clothing and goggles
appropriate for the project and type of stripper.
4. Use paint strippers outdoors if possible. If you must
use them indoors, cross-ventilate by opening all doors
and windows. Make sure there is fresh air movement
throughout the room. Ventilate the area before,
during, and after applying and stripping. Never use
any paint stripper in a poorly ventilated area. If
work must be done indoors under low ventilation
conditions, consider having the work done
professionally instead of attempting it yourself.
5. If you must work indoors, always work so the stripper
fumes are blowing away from you and to the outside. A
fan can be used to improve cross-ventilation and to
ensure fresh air movement. A fan is particularly
important for nonflammable products that evaporate
quickly, such as methylene chloride. Electrical sparks
from fans may increase the chance of flammable paint
strippers fumes to catch fire.
6. Do not use flammable paint strippers near any source of
sparks, flame, or high heat. Do not work near gas
stoves, kerosene heaters, gas or electric water
heaters, gas or electric clothes dryers, gas or
electric furnaces, gas or electric space heaters,
sanders, buffers, or other electric hand tools. Open
flames, cigarettes, matches, lighters, pilot lights, or
electric sparks can cause the chemicals in the paint
strippers to suddenly catch fire.
7. Only strip paint with chemicals that are marketed as
paint strippers. Never use gasoline, lighter fluid, or
kerosene to strip paint.
8. Dispose of paint strippers according to the
instructions on the label. If you have any questions,
ask your local environmental sanitation department
about proper disposal.
TYPES OF PAINT STRIPPERS
SOLVENT-BASED STRIPPERS
Most paint strippers are solvent-based. Solvents dissolve
the bond between wood and paint. Solvents also can dissolve
other materials, including the latex or rubber of common
household or dish washing gloves. Some solvents will irritate or
burn the skin. Some solvents may cause serious health effects
even if contact does not immediately cause pain. In addition,
many solvents evaporate quickly and you can easily inhale them.
Inhalation of these solvents can produce health effects
immediately or years after exposure.
It is especially important to use paint strippers containing
solvents that evaporate quickly either outdoors or in an indoor
area with strong fresh air movement. Some paint strippers
contain solvents that do not evaporate quickly. When using these
strippers indoors, be sure to open windows and doors to provide
fresh air movement in and out of the work site. You should
always follow the manufacturer's instructions and safety
precautions. Use the amount of stripper recommended by the
manufacturer to avoid buildup of harmful fumes.
The different types of solvent-based paint strippers and
their potential hazards and safety precautions are:
== Methylene chloride (also called dichloromethane, or DCM) --
Methylene chloride is the most commonly used chemical in
paint strippers. Methylene chloride products come in two
varieties. One type is nonflammable, while the other type is
flammable. The flammable paint strippers have less methylene
chloride but have other flammable chemicals, including acetone,
toluene, or methanol.
Methylene chloride causes cancer in laboratory animals. The
U.S. Environmental Protection Agency (EPA) and the U.S. Consumer
Product Safety Commission (CPSC) consider the chemical to be a
potential cause of cancer in humans. Methylene chloride
evaporates quickly, and you can inhale it easily. Breathing high
levels of methylene chloride over short periods can irritate the
eyes, skin, nose, and lungs. It can also cause dizziness,
headache, and lack of coordination. Your body changes some
inhaled methylene chloride to carbon monoxide. Carbon monoxide
lowers the blood's ability to carry oxygen. This can cause
problems for people with heart, lung, or blood diseases who use
methylene chloride paint strippers indoors without fresh air
cross-ventilation. High exposures to methylene chloride for long
periods can also cause liver and kidney damage.
- It is very important to reduce your exposure to methylene
chloride vapors.
- It is very important to have a lot of fresh air when
using methylene chloride products.
- Use methylene chloride paint strippers outdoors if
possible. If you must use them indoors, open all doors and
windows to ensure that the fresh air is moving in and out of the
room.
- For indoor use of nonflammable methylene chloride
strippers, also use a fan to keep fresh air moving throughout the
work area. Electrical sparks from fans may increase the chance
of flammable paint strippers fumes to catch fire.
- The safest place to use flammable methylene chloride
strippers is outdoors away from any source of sparks, flame, or
high heat.
== Acetone, toluene, and methanol --
These chemicals are commonly used together. All three
chemicals evaporate quickly and are very flammable. Breathing
high levels of these chemicals can cause a variety of effects,
including drowsiness, dizziness, and headache. Breathing high
levels of toluene may harm unborn children. Breathing very high
levels for a long period may cause brain damage. Toluene and
methanol are poisonous if swallowed.
- To avoid fire and health problems, it is very important
to use products containing these chemicals only in areas with
plenty of fresh air.
- Do not work near an open flame, pilot lights, or
electrical sparks when using flammable paint strippers. Do not
use strippers near gas stoves, kerosene heaters, gas or electric
water heaters, gas or electric clothes dryers, gas or electric
furnaces, gas or electric space heaters, sanders, buffers, or
other electric hand tools.
== N-methylpyrrolidone (NMP) --
Excessive contact with NMP may cause skin swelling,
blistering, and burns. These skin reactions may not appear until
some time after exposure. N-methylpyrrolidone can readily get
into the body through the skin and may cause health problems.
NMP may cause reproductive problems and harm to unborn children.
- It is very important to wear chemical-resistant gloves
and avoid skin contact when using this solvent.
- Wash hands immediately after use, even when wearing
gloves.
- Gloves should fit properly and be chemical-resistant.
Common kitchen latex gloves do not provide enough protection.
- Avoid using this product for extended periods in an
enclosed area without open doors or windows to the outside for
cross-ventilation.
== Dibasic esters (DBE), including dimethyl adipate ester,
dimethyl succinate ester, and dimethyl glutarate ester --
Much less is known about the possible health effects of
these chemicals than about most of the other paint stripping
chemicals. Some people using DBE products without fresh air have
reported temporary blurred vision. Repeatedly breathing DBE
damages the cells lining the nose of laboratory animals. Some
strippers include a mixture of DBE products and NMP.
- Avoid using this product for extended periods in an
enclosed area without open doors or windows to the outside for
cross-ventilation.
- Use appropriate protective clothing and provide fresh air
to the work site when using these products.
CAUSTIC-BASED STRPPERS (NOT FLAMMABLE)
== Caustic alkalis --
Caustic alkalis react with the paint coating and loosen it
from the surface. One of the chemicals in this type of stripper
is sodium hydroxide (lye). Some people do not use caustic
alkalis because caustic products can darken wood and raise the
grain. Caustics can cause severe burns to skin and eyes even on
short contact. Therefore, be very careful to keep caustic
chemicals away from skin and eyes and wear protective clothing.
If contact occurs, wash off immediately with cold water.
Caustics are also highly toxic if swallowed.
- It is very important to avoid skin and eye contact when
using caustic alkalis.
- Use gloves that fit properly and are appropriate for
caustic alkalis.
- Wear appropriate protective clothing and goggles when
using caustic alkalis.
OTHER TYPES OF PAINT STRIPPERS
Some paint strippers have a citrus smell or make
"environmentally friendly" claims. However, these paint
strippers may be hazardous despite the smell and environmental
claims.
- It is important to use appropriate protective clothing
and fresh air for cross-ventilation when using these products.
For more information on indoor air quality, contact:
U.S. Environmental
Protection Agency
Washington, DC 20460
800-438-4318
CPSC 423 009509
EPA 747-F -95-002
Additional Household Hazardous Waste Resources by the Home Air Purifier Expert
Here are some of our other information packed guides we recommend you explore in your search for information about controlling Household Hazardous Wastes and Chemicals like those found in paints, stains, varnishes, thinners, and laquers:
-
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